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叔胺的氮氧化物用活性试剂（如乙酸酐）处理，重排生成 N,N-二取代乙酰胺和醛的反应。此反应最常见的应用就是甲基叔胺脱甲基或者苄基叔胺脱苄基。
图片来源：https://cheminfographic.wordpress.com/2017/10/14/40-polonovski-reaction-1927/
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